Last edited by Mazujora
Sunday, August 2, 2020 | History

6 edition of Ion-Transfer Kinetics found in the catalog.

Ion-Transfer Kinetics

by J. R. Sandifer

  • 160 Want to read
  • 35 Currently reading

Published by Wiley-VCH .
Written in English

    Subjects:
  • Physical Chemistry,
  • Science,
  • Science/Mathematics,
  • Chemistry - Physical & Theoretical,
  • Science / Chemistry / Physical & Theoretical,
  • Energy,
  • Chemical kinetics,
  • Ionic mobility

  • The Physical Object
    FormatHardcover
    Number of Pages142
    ID Numbers
    Open LibraryOL10303737M
    ISBN 100471185612
    ISBN 109780471185611

    Complementarily, kinetics of charge transfer and ion transfer are treated in some detail in relation to conductance, kinetics of surface processes and electrode-kinetics involving solid-state processes. This chapter will be of major interest to electrochemists and physicists in the semiconductor field and that involving ionic solids. Physical properties of biopolymers and kinetics of cell metabolic reactions are responsible for molecular characteristics of biological processes. Free PDF Books: Fundamentals of Biophysics – A biomacromolecule as the main structure element in a cell is considered in biophysics as a peculiar molecular machine where energy is transformed.

    The rate of TEA+ ion transfer across the water/1,2-dichloroethane interface has been measured using steady-state voltammetry at a capillary with an orifice of nano-sized dimension. It is found that the average rate constant for TEA+ transfer from water to oil and from oil to water is cms−1. The results are repeatable using the same capillary. This value. Description; Chapters; Supplementary; An elementary act of charge transfer determines a variety of phenomena in physics, chemistry and biology. The study of charge transfer processes has developed together with general progress in theoretical physics and in fast high resolution spectroscopy, so that research deals now with a broad class of systems, materials and environmental conditions.

    Our Book among Other Books on Chemical Kinetics The Logic in the Reasoning of This Book How Chemical Kinetics and Mathematics are Interwoven in This Book Ion-Transfer Kinetics. by J. R. Sandifer. Fuel Cells. Propellants, Explosives, Pyrotechnics. Purchase Options. Hardcover. $ BUY. A comprehensive review of advances in one of today's most technologically important research fields. Spurred on by society's increasingly urgent demand for an inexpensive, environment-friendly alternative to the internal combustion engine, research into electrocatalytic fuel cells has yielded many exciting advances in the past few years. This rapid rate of progress, however, has created a.


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Ion-Transfer Kinetics by J. R. Sandifer Download PDF EPUB FB2

Buy Ion-Transfer Kinetics on FREE SHIPPING on qualified orders Ion-Transfer Kinetics: Sandifer, J. R.: : Books Skip to main content. The book introduces the reader to the principles of Ion-Transfer Kinetics book kinetics based on an assumed knowledge of calculus, electrostatics, and thermodynamics.

These principles are presented in a simply way and their generality is abundantly illustrated with real examples. The book also supplies sufficient instruction in experimental methodology to allow the reader to study the principles of ion. The book also supplies sufficient instruction in experimental methodology to allow the reader to study the principles of ion- transfer kinetics experimentally.

The principles are so well developed mathematically that the reader can even write computer programs to simulate the ion-transfer properties of hypothetical materials incorporated into Pages: Additional Physical Format: Online version: Ion-transfer kinetics.

New York: VCH, © (OCoLC) Document Type: Book: All Authors / Contributors. The zinc metal is recognized as one of the most promising anodes for Zn-based batteries in an energy-storage system. However, the deposition and transfer of bivalent Zn 2+ into the host structure suffer from sluggish kinetics accompanying the side-reactions at the interface.

Herein, we report a new class of Zn anodes modified by a three-dimensional (3D) nanoporous ZnO architecture coating on a. Ion-Transfer Kinetics: Principles and Applications | Sandifer, James R.

| ISBN: | Kostenloser Versand für alle Bücher mit Versand und Verkauf duch Amazon. Films with thicknesses of ~18 nm and flat surfaces with roughnesses of less than 1 nm were model systems for clarifying the kinetics of Li-ion transfer at the electrode/electrolyte interface.

The Li-ion transfer characteristics at the interface between the LiCoO 2 electrode and the electrolyte (LiPF 6, ethylene carbonate + diethyl carbonate.

The kinetics of tetraethylammonium (TEA +) ion transfer across the water/1,2-dichloroethane interface was studied using electrochemical impedance spectroscopy and steady-state liquid/liquid interface was supported at the tip of a microcapillary.

A novel capillary design methodology has advantageously allowed the use of the same microcapillary in a number of. Double layer effects on the kinetics of the Cs + ion transfer across the water/nitrobenzene interface were studied by an ac polarographic technique.

Apparent kinetic parameters agree well with those reported previously. By applying the Frumkin-type correction based on the Gouy-Chapman theory, the non-linear Tafel plots were inferred indicating some dependence of the charge.

The Li-ion desertion process of a single LiFePO4 particle with a diameter of nm in aqueous media at high potential is investigated by stochastic collision of the particle at a microelectrode. No extra additive, such as polymeric binder or conductive carbon, is involved in this stochastic measurement.

The ion diffusion inside the particle is proved to be the rate-determining step that. Potassium and sodium-ion transfer kinetics were compared for the intercalation reactions into the KVPO4F positive electrode material in acetonitrile- and ethylene carbonate-based electrolytes.

Kinetics of lithium-ion transfer at the interface between oxide-negative electrodes and organic electrolytes was studied using a Li 4 Ti 5 O 12 thin-film electrode and ac impedance spectroscopy.

We evaluated the activation energies of the interfacial lithium-ion transfer from the temperature dependences of the interfacial conductivities.

The kinetics of the ion transfer across the liquid|liquid interface is studied by means of a thin film-modified electrode in combination with square-wave voltammetry. Cyclic voltammetry at micropipet electrodes is applied to the kinetic study of ion transfer at liquid/liquid interfaces.

Simple and facilitated transfer of an ion that is initially present outside a tapered pipet was simulated by the finite element method, enabling complete analysis of the resulting transient cyclic voltammogram (CV) with a sigmoidal forward wave followed by a peak-shaped. Show Summary Details.

kinetics are thus limited by electron transfer at the solid-solid (carbon-Li x FePO 4) interface, rather than by ion transfer at the liquid-solid interface, as previously assumed. The proposed experimental method generalizes Chidsey’s method for phase-transforming particles and porous electrodes, and the results show the need to incorporate.

The kinetics are thus limited by electron transfer at the solid–solid (carbon-Li x FePO 4) interface rather than by ion transfer at the liquid–solid interface, as previously assumed.

The. THEORY OF THE KINETICS OF ION TRANSFER ACROSS LIQUID/LIQUID INTERFACES. Nanoelectrochemical measurements are also plagued by difficulties in characterizing nanometer‐sized interfaces and conductor/insulator boundaries.

In this review, we discuss the results of fast electron and ion transfer kinetics measurements at nanointerfaces, along with related reliability problems and some approaches to fixing them.

Unlike many other references, Radiation-Chemical Processes in Solid Phase analyzes experimental data on radiolysis in terms of solid-state physics. It traces the effect exerted by media from primary processes of radiation-substance interaction to final authors consider the main chemically active elementary excitations arising under irradiation of solids and discuss the mechanisms.

As noted earlier the more rapid demise in sulphate exchange kinetics compared with those for chloride exchange is a common feature of the in-service deterioration of anion exchangers. The influence of foulants is likely to be cumulative but, because the within bead ion transfer for a new resin is relatively fast, there may be a significant.Ion transfer across an immiscible solution interface is detected as a flow of the ion or a current driven by applied potential[ 1, The current-potential rela- tion characterizes the kinetics of the ion-transfer.

It has been elucidated by combination[ of the.In Section “Lewis Electron Dot Diagrams,” we saw how ions are formed by losing electrons to make cations or by gaining electrons to form anions. The astute reader may have noticed something: Many of the ions that form have eight electrons in their valence shell.

Either atoms gain enough electrons to have eight electrons in the valence shell and become the appropriately charged anion.